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Another generation of OSPs is designed to survive exposure to multiple high-temperature soldering operations. These chemicals are normally based on benzimidazole with attached functional groups to add molecular weight and thermal resistance. Substituted phenylimidazole and OSP systems with metal codeposits have been used as well. The intent of the new generation of OSP is to withstand Pb-free soldering temperatures. These high-temperature OSP coatings, made for use with Pb-free alloys and the associated fluxes, can be deposited at higher thicknesses and may be measured as high as 1.0 micron.

M(s) = K,,~A P(s)

Fabrication Process Table 32.5 show the fabrication process for OSP, including chemicals and dwell times. Almost universally, OSP is applied in conveyorized equipment. The cleaner and microetch may use flood or spray application, but OSP is applied using flood. Because the OSP process is very mild to the PCB materials, rinsing is very important to ensure that contamination from all prior fabrication steps is removed. Often, OSP is applied when the PCB is in part form after the PCB has been electrical tested, routed, and depanelized. This is to preserve the

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The purpose of the analysis is not to show how an analysis should be made, but rather to explain why a flow loop behaves the way it does. Because many dynamic elements are present, a11 of the same order of magnitude, dynamic gain is high. The proportional band of a flow controller is rarely less than 100 percent, making reset mandatory. Where the valve and transmitter are in the same line, the period of oscillation will invariably fall within 1 to 10 sec. The presence of noise precludes the use of derivative. As long as these factors are appreciated, there is little reason to spend time analyzing flow loops.

TABLE 32.5 Process Flow for Organic Solderability Preservative Process Cleaner Microetch Pre-Dip OSP Chemicals Aqueous solvents, detergents, and emulsifiers. Acid can help undercut residues and remove thick copper oxides. 1 2 m of Cu is oxidized to Cu++ and dissolved. Normally, the predip employs ingredients of the OSP bath without the OSP chemical itself. OSP, acetic or formic acid, source of copper or other metals. Time (min/) 1 4

(11.13)

0.5 0.5 1.0

fragile OSP surface, which is sensitive to handling, contamination, and fingerprints. The OSP parts should stabilize at room temperature and controlled humidity before packaging, as any moisture in the package can turn the OSP surface black. OSP thickness is normally determined by indirect sampling. No method exists for determining the OSP thickness during production on the actual PCB. Instead, a sample coupon is processed along with the production parts.The coupon is immersed in an acid/solvent solution that dissolves the coating. The solution is transferred to a UV-VIS cell, where the absorbance of light allows the estimation of the thickness of OSP on the coupon. That measurement is used as a quality control for the production boards. The lack of a true thickness measurement control is a key issue to OEMs that require control metrics. If the OSP coating is too thin, the PCBs will have inadequate protection. If the coating is too thick, there is a possibility for poor solder wetting and poor PTH filling. The OSP coating is invisible to the eye, so there is no way to inspect for unprotected copper if the OSP coating was not applied correctly.

For illustration, assume that the measuring element converts concentration of A to a pneumatic signal. Specifically, the output of the measuring element varies from 3 to 15 psig as the concentration of A varies from 0.01 to 0.05 lb mole A/ft3. We shall assume that the concentration measuring device is linear and has negligible lag. The sensitivity (or gain) of the measuring device is therefore 15 - 3 K, 0.05 - 0.01 = 300 psi/(lb mole/ft3) Since czS is 0.0244 lb mole/ft3, the normal signal from the measuring device is 0.0244 - 0.01 0.05 - 0.01 (15 - 3 ) + 3.0 = 4.32 + 3.0 = 7.32 psig The equation for the measuring device is therefore b = 7.32 + Km(c2 - 0.0244) (11.14) where b is the output pressure (psig) from the measuring device. In terms of deviation variables, Eq. (11.14) becomes B = K,C2 (11.15)

Advantages and Disadvantages Table 32.6 compares the advantages and disadvantages of using OSP as a surface finish.

TABLE 32.6 Comparing the Advantages and Disadvantages of OSP OSP Advantages Flat; fine-pitch assembly Least expensive finish Simple process Widely available Cu/Sn solderjoint No Pb Reworkable High productivity at fabrication OSP disadvantages No direct thickness measurement High surface contact resistance Poor PTH soldering Shorter shelf-life Exposed copper on final assembly Not inspectable before assembly Degrades with multiple reflow Handling-sensitive Problems with paste misprint cleaning

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