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Failure Modes The OSP process is simple, so few failure modes exist at fabrication due to chemical stability. Aggressive microetch and poor rinsing can result in attack at the junction of solder mask and exposed PCB metal, especially if nickel-gold has been selectively deposited on edge fingers. Galvanic attack at this interface can cause electrical opens. PCBs using selective nickel-gold can also suffer from deposition of OSP on the gold surface. OSP on copper prevents good

= c2-Q. The transfer function for the measuring device is therefore (11.16)

electrical test contact and in-circuit testing. OSP deposition on selective gold can prevent the intended contact functionality of the gold pad. Skip plating can be a concern. Very thin solder mask residues will prevent OSP coating. Because the OSP coating is invisible, it cannot be inspected, so skip plating will lead to non-wetting at assembly. OSP is the coating most sensitive to handling, storage, and shelf-life. Copper under OSP oxidizes with time and heat, so weak fluxes present soldering issues. The Pb-free temperature increase has narrowed the OSP process window to the point where PTH solderability may not meet IPC standards.[1 3]

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Silver was chosen as a PCB surface finish from the earliest days of PCB fabrication due to some inherent advantages. Silver is the best electrical conductor and exhibits the lowest contact resistance of any metal. As a precious metal, it is more resistant to oxidation than other more base metals. On early PCBs, electroplated silver was discovered to form metal dendrites between conductors. During the 1990s, new immersion silver was introduced as an HASL alternative, and users developed data showing that dendrite formation was not an issue. With the Pb-free transition, immersion silver gained widespread use. OEMs with specific needs specified silver to overcome issues with other finishes. Immersion silver is a galvanic displacement process with a typical thickness range of 0.1 to 0.4 mm. The fabrication process is easy, but the coating can suffer from tarnish when left exposed after assembly in field use. Heavy tarnish can be a predictor for corrosion and functional loss.

A measuring device that changes the units between input and output signals is called a transducer; in the present case, the concentration signal is transduced to a pneumatic signal.

Chemical Coating The PCB copper is prepared using separate cleaning and microetch steps. Over time, these steps can be taken for granted, but improper use can cause many defects. The predip bath removes excess acidity from the PCB and prevents chlorides from entering the silver bath, where silver chloride would quickly precipitate. The silver bath is quite simple chemically, relying on the galvanic displacement of less noble copper with two atoms of more noble silver. Proper rinsing and drying is essential.

Fabrication Process Table 32.7 shows the fabrication process for immersion silver surface finish, including the chemicals used and dwell times.

For convenience, we shall assume the controller to have proportional action, in which case the relation between controller output pressure and error is (11.17) p = ps + Kc(c~ - b) = ps + K,E where CR = desired pneumatic signal (or set point), psig K, = controller sensitivity, psig/psig E =error = CR-b,PSifJ

TABLE 32.7 Process Flow for Immersion Silver Process Cleaner Microetch Predip Silver Postdip (optional) Chemicals Aqueous solvents, detergents, and emulsifiers. Acid can help undercut residues and remove thick copper oxides. 1 2 mm of Cu is oxidized to Cu++ and dissolved. Normally, the ingredients of the silver bath without the silver metal itself. Silver, acid, grain refiners, chelation Ag+ + Cu(0) Ag(0) + Cu++ Can be an antitarnish or an extra cleaner for demanding ionic cleanliness applications. Time (min) 1 4 0.5 1.0 0.5 0.5 3.0

The thermodynamic state of a system can be defined from its pressure, enthalpy, and volume. If a gas phase alone is present, pressure and

Most immersion silver in large production is applied in conveyorized equipment. The cleaner and microetch may use flood or spray application, but the silver solution is applied using flood. Because the silver process is very mild to the PCB materials, rinsing is very important to ensure that contamination from all prior fabrication steps is removed. Often, silver is applied in part form after the PCB has been routed, depanelized, and electrically tested. This is to preserve the silver surface, which can be sensitive to handling, contamination, and fingerprints. In smaller-scale production and prototype manufacturing, silver can be applied in vertical process tanks.

(11.18)

Advantages and Disadvantages Table 32.8 compares the advantages and disadvantages of using immersion silver as a surface finish.

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